000 02364cab a2200289Ia 45 0
001 u208841
003 SIRSI
008 120426s2002 ua ss b eng d
040 _aEAL
041 _aeng
_bara
090 _aART ZJAR V29 No6 13
100 1 _aSalib, Madlain M.
240 1 0 _aZagazig journal of agricultural research, 2002 v. 29 (6)
_h[electronic resource].
245 1 2 _aA comparative study on some thermodynamic approaches for predicting the cation exchange isotherms in binary systemsl
_h[electronic resource].
246 _aدراسة مقارنة عن بعض فروض الديناميكا الحرارية للتنبؤ بسلوك خاصية التبادل الكاتيوني في النظم الثنائية (Na-Ca and K-Ca)
300 _ap.1987-2008.
504 _aIncludes references.
520 _aThe current study aimed to assess the applicability of some exchange isotherm approaches, i.e., Gains-Thomas (equivalent fraction) and Argersinger-Vanselow (mole fraction) for descriptiag the cation adsorption ia soil system.To achieve this target, an experimeat was carreid out on the exchange isotherms for binary systems ofNa-Ca and K-Ca in an aggregated sandy clay loam soil using batch and miscible-displacement techniques. The obtained results revealed that the selectivity coefficient of Na-Ca exchaage isotherm, as calculated using Gains-Thomas (KGTNa), approximately constant at all the studied solution conceatrations, except that those of low Na:Ca ratios, which showed slightly high values. Whereas, KvNa of Argersinger-Vanselow exhibited gradually decrease with increasing the Na:Ca ratios. As for the calculated true exchange constant, using the integral equation of the conventional thermodynamic approaches or Rothmund-Kornfeld formulation, that take into consideration the activity of adsorbed phase, appeared approximately constant values for the two conventions at all the studied solution concentrations.
546 _aSummary in Arabic.
650 0 _aThermodynamica
650 0 _aAtmospheric temperature.
650 0 _aBinary systems (Metallurgy)
_xChemical structure.
650 0 _aSoil absorption and adsorption.
773 0 _tZagazig Journal of Agricultural Research.
_g2002.v.29(6)
_x1110-0338
_7nnas
_wu158356
856 4 0 _uhttp://nile.enal.sci.eg/EALE/2002/ZJAR/2902/6/1987.pdf
_zFull Text Article.
596 _a1
942 _cAR
_2lcc
999 _c58532
_d58532